Specifically for 1969, all 4-barrel engines came with 12-bolt rears, with any exceptions noted. That includes the regular fuel 350 255 horse (LM1) (manual transmissions or F40 only) & premium fuel 350 300 horse (L48) (all transmissions). Also any lesser engines included a 12-bolt when F40 suspension was ordered (including 230, 250, 307, 350 2-barrel L65). All B07 Police option Chevelles also included a 12-bolt rear.
The LM1 350 was dropped later in production and replaced with the L65. The L65 includeded a 10-bolt by default regardless of transmission.
Curiously, the Chevrolet specs show the 2.56:1 rear axle was 12-bolt only, meanwhile the AMA specs show the 2.56:1 & 2.73 rear axles were 10-bolt only. (Inconsistencies in Chevrolet vs. AMA documents like this are most troubling, especially when it involves emissions equipment, police & roadside inspections!)
The 2.56 ratio was an optional economy ratio available right down to the 230 six when a Turbohydramatic was ordered as long as it wasn't a wagon or having a/c.