Kelly,
Was this ORIGINALLY a 3spOD car? If so, is the harness all there and intact? If the answer to that is yes, do you have a good connection at the relay and is the relay in good condition (the relay for an OD tranny looks kind of similar to a horn relay).
The OD normally does not engage until a speed of about 30mph is reached. But, actually, its not the vehicle speed which determines when OD is engaged, it's the speed of the tranny tailshaft. For example, MOST 3spOD cars came with a 4.11 rear. So, if your car had a 4.11, and you changed the rear gears to a 3.31, then it may be 40mph before the OD kicked in. The 3spOD trannys have both a govenor and an elec solenoid on the tail housing. At a certain shaft speed, the governor sends current to the relay, and then the relay sends 12volts to the solenoid to actuate a pawl that engages or disengages the sun gear (the sun and planetary gears is what makes the OD). So, after all this, it very possibly is NOT the tranny itself, but an electrical circuit problem. Make sure all electrics are connected, in good condition and check the solenoid (apply 12volts to the solenoid terminal) to be sure it is working (the kickdown switch on the throttle linkage serves to kick the tranny out of OD upon hard, full throttle acceleration).
As I'm sure you have noticed, there is also a mechanical shift lever on the side of the tail housing. This lever is engaged/disengaged by a cable with the handle mounted under the dash. Be sure this is going full travel. To test this, when the OD is engaged (handle pushed in), and you are driving down the road, let off of the throttle, the car should "free wheel". Shift it out of OD (stop the car to do this) and when driving down the road and letting off the gas, the car should be slowed down by engine compression just like a regular manual tranny would do (that's what you have when OD is disengaged).
Before I got my first Muncie, I drove a 3spOD and loved it (if you knew how to make one work, you could get 6spds from one)! But, unfortunately, the 3spOD was not up to the task of staying together behind a performance V-8. After a couple of rebuilds, I got my first Muncie. That was back in the 60s (but I still remember how they worked, kind of like riding a bike).