Be aware if it's a BBC with flat top pistons it may not contact the piston enough to stop it. I ran into this last week with a friend's car. Also, you should loosen the rockers on that cyl enough to free the pushrods so the valves don't open against the stop. Remove all spark plugs to make the engine easier to turn and if you loosen all the rockers it will be easier yet. Disconnect the battery so the there's no way the started can accidentally get engaged.